All three of the Skull Squadron VF-1S valks shown in DYRL are #001. Obviously, Roy was squad leader until Max took over when Roy, Hikaru, Misa, Minmay, and Kaifun were captured by the Zentraedi. Then Hikaru got to be Skull 001 after Max disappeared during his dual with Millia.
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the number i got is from the yamato version. I havent actually seen the original show, I simply love the valkyries. so blame yamato!